Boron Oxide (Boric Oxide, Anhydrous Boric Acid, DiBoron Trioxide)

Boron Oxide (Boric Oxide, Anhydrous Boric Acid, DiBoron Trioxide)

Description

Boron Oxide (Glassy, Anhydrous), also known as Diboron Trioxide (B₂O₃), is the oxide of boron with the formula B₂O₃. It is a colorless transparent solid, almost always glassy (amorphous), which can be crystallized only with great difficulty. It is also called boric oxide or boria. It has many important industrial applications, chiefly in ceramics as a flux for glazes and enamels and in the production of glasses.

Additional information

CAS No

1303-86-2

EC No

215-125-8

Chemical Formula

B₂O₃

Synonyms

Boric Oxide, Boron Trioxide, DiBoron Trioxide, Anhydrous Boric Acid

Physical State

Solid, Glassy

Color

White

Odor

Odorless

Flammability

Non-flammable

Flash Point

Non-flammable

Usage & Benefits

Usage and Benefits:

Glass: It is used as an agent to lower the fusing point and to increase the thermal expansion coefficient in glass production. Moreover, it improves the scratch resistance and acid resistance of glass and enhances its color and gloss properties.

Ceramics: Boron oxide is used in the production of ceramic and enamel glazes. Its functions are to regulate the coefficient of thermal expansion between the glaze and the material to be glazed; to ensure that the index of refraction of the glaze is high; to increase the mechanical properties and the scratch resistance of the glaze and to increase resistance against water and chemicals.

Boron chemicals: In the production of boron chemicals, it is used in the production of inorganic compounds such as boron hydrides, boron nitrides, and is used as a catalyst in the production of organic boron compounds such as boric acid esters.

Metallurgy: It is used as flux in the metallurgy industry as it is a good solvent for metal oxides.

Electric-Electronic: It is used in the production of Ga-As (Gallium-Arsenic) semiconductors.

Properties

Physical and Chemical Properties:

Synonyms Boric Oxide, Boron Trioxide, DiBoron Trioxide, Anhydrous Boric Acid
CAS# 1303-86-2
Formula B2O3
pH 4.4
pH Solution 1% @ 20°C
Specific Weight 2.17 g/cm³
Solubility in Water 2.7% @ 20°C
Pour (Bulk) Density 1.10 g/cm³
Molecular Weight 69.62 g/mol
Melting Point 450°C
Boiling Point 1860°C
Heat Capacity 16.2 J/g°C
Thermal Conductivity 0.345 W/mK
Specific Surface Area < 1 m²/g
Diffusion Coefficient 1.1×10⁻⁵ cm²/s
Surface Tension 68.17 mN/m (1.0% aqueous solution by weight)
Colorimetry Test 96.43 (average L value)
Physical State Solid
Colour White
Odour Odourless
Odour Threshold N/A
Flammability (Solid, Gas) Non Flammable
Flash Point Non Flammable
Vapour Pressure Negligible @ 20°C
Density 1838 kg/m³ (Type: ‘density’, Temp.: 21.5°C)
Solubility Water: 2.7% @ 20°C

Specifications

Chemical Specification:

Component Content
B2O3 98.00% min
SO4 500 ppm max
Cl 10 ppm max
Fe 35 ppm max

Chemical Content:

Component Content
B2O3 98.0% min
B 30.4% min
Water-soluble B 30.4% min
SO4 500 ppm max
Cl 10 ppm max
Fe 35 ppm max

Heavy Metal Content:

Component Content (mg/kg)
As 0.600 max
Cd <0.005
Pb <0.010
Cr <0.005
Hg <0.010

Particle Size:

Size Content
+0.250 mm 35% max

Solution Properties

Graph and table showing solubility of boron oxide in water increases significantly with temperature, from 1.44 g/100g at 0°C to 18.30 g/100g at 100°C.

 

Graph and table displaying decreasing pH values of boron oxide solution as concentration increases from 1 to 4 grams per 100g water.

(708) 249-3272